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Role of the water of crystallization in the Mössbauer spectra of some low-spin ferric and high-spin ferrous compounds. Its implications in comparative studies

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Abstract

Mössbauer spectra of low-spin ferric and high-spin ferrous compounds may be sensitive to the local humidity during the measuring process or to other parameters associated with the hydration degree of the sample. This effect is related to the location of water molecules around the t2g orbitals (dxy, dxz, dyz). The results indicate that for comparative studies all Mössbauer measurements must be carried out in well standardized conditions.

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References

  1. E. Reguera, J. F. Bertran,Hyperf. Interact., 88 (1994) 49.

    Google Scholar 

  2. A. Vértes, T. Székely, T. Tarnóczy,Acta Chim. Acad. Sci. Hung., 63 (1970) 1.

    Google Scholar 

  3. E. Reguera, J. F. Bertran, A. Dago, C. Diaz, J. Blanco, S. Rondon,Hyp. Int., 53 (1990) 391.

    Google Scholar 

  4. J. Fernandez-Bertran, J. Blanco, E. Reguera,Spectrochim. Acta, 46A (1990) 685.

    Google Scholar 

  5. J. Fernandez-Bertran, E. Reguera, J. Blanco,Spectro-Chim. Acta, 46A (1990) 1679.

    Google Scholar 

  6. E. Reguera, J. Fernandez-Bertran, J. Duque,Polyhedron, 13 (1994) 479.

    Google Scholar 

  7. E. Reguera, J. Fernandez-Bertran, L. Nuñez,Polyhedron, 13 (1994) 1619.

    Google Scholar 

  8. E. Reguera, J. Fernandez-Bertran, J. Miranda, A. Dago,Hyperf. Interact., 77 (1993) 1.

    Google Scholar 

  9. W. E. Bailey, R. J. Williams, W. O. Milligan,Acta Cryst., B29 (1973) 1365.

    Google Scholar 

  10. X. L. Xu, R. E. Emmenegger, F. Hulliger,Eur. J. Solid State Inorg. Chem., 27 (1990) 537.

    Google Scholar 

  11. F. Hulliger, M. Landolt, H. Vetsch,J. Solid State Chem., 18 (1976) 283.

    Google Scholar 

  12. W. Petter, V. Gramlich, F. Hulliger, H. Vetsch,Eur. J. Solid State Inorg. Chem., 29 (1992) 65.

    Google Scholar 

  13. D. F. Mullica, E. L. Sappenfield, H. O. Perkins,J. Solid State Chem., 73 (1988) 65.

    Google Scholar 

  14. A. Ludi, H. U. Güdel,Structure and Bonding, 14 (1973) 1.

    Google Scholar 

  15. J. B. Ayres, W. H. Waggoner,J. Inorg. Nucl. Chem., 33 (1971) 721.

    Google Scholar 

  16. D. F. Mullica, D. B. Tippin, E. L. Sappenfield,J. Cryst. Spectrosc. Res., 21 (1991) 81.

    Google Scholar 

  17. E. Reguera, J. Fernandez-Bertran, A. Dago, A. Gomez,Inorg. Chim. Acta, (1994) (in print).

  18. E. Reguera, J. Fernandez-Bertran, C. Diaz, J. Molerio,Hyp. Int., 73 (1992) 285.

    Google Scholar 

  19. E. Reguera, J. Fernandez-Bertran, A. Dago, C. Diaz,Hyp. Int., 73 (1992) 295.

    Google Scholar 

  20. E. Reguera, J. Fernandez-Bertran, J. Miranda, C. Portilla,J. Radioanal. Nucl. Chem., Letters, 165 (1992) 191.

    Google Scholar 

  21. E. Reguera, J. Fernandez-Bertran,Eur. J. Solid State Inorg. Chem., 31 (1994) 1021.

    Google Scholar 

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Authors and Affiliations

  1. Division of Chemistry, National Center for Scientific Research, Ave. 25 and 158 Str., Cubanacan, P. O. Box 6990, Havana, Cuba

    E. Reguera & J. Fernández-Bertrán

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  1. E. Reguera
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  2. J. Fernández-Bertrán
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Reguera, E., Fernández-Bertrán, J. Role of the water of crystallization in the Mössbauer spectra of some low-spin ferric and high-spin ferrous compounds. Its implications in comparative studies. Journal of Radioanalytical and Nuclear Chemistry Letters 200, 443–455 (1995). https://doi.org/10.1007/BF02162885

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  • DOI: https://doi.org/10.1007/BF02162885

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