Skip to main content
SpringerLink
Log in

Nachweis von Scilliglaucosidin in den Zwiebeln vonBowiea volubilisHarvey

  • Kurze Mitteilungen
  • Published:
Experientia Aims and scope Submit manuscript

Summary

Hellebrigenin was converted to Scilliglaucosidin-19-ol and 3-Epi-Scilliglaucosidin-19-ol. This proves the correctness of the assumption ofStoll et al. 3 that the aldehydic group of Scilliglaucosidin is in position C-10.

Comparison of a reduction product of Nabogenin, a substance isolated earlier from the bulbs ofBowiea volubilis Harvey, with Scilliglaucosidin-19-ol and 3-Epi-Scilliglaucosidin-19-ol showed its identity with the first named compound. This proves that the so called Nabogenin was a mixture consisting mainly of Scilliglaucosidin.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literatur

  1. A. Stoll, A. von Wartburg undJ. Renz, Helv. chim. Acta36, 1531 (1953);36, 1538 (1953).

    Article  CAS  Google Scholar 

  2. J. Schmutz, Helv. chim. Acta32, 1442 (1949).

    Article  CAS  Google Scholar 

  3. C. Mannich undG. Siewert, Ber. dtsch. chem. Ges.75, 737 (1942).

    Article  Google Scholar 

  4. R. P. A. Sneeden undR. B. Turner, J. Amer. chem. Soc.77, 130 (1950).

    Article  Google Scholar 

  5. A. Hunger undT. Reichstein, Ber. dtsch. chem. Ges.85, 635 (1952).

    Article  CAS  Google Scholar 

  6. A. Katz, Pharm. Acta Helv.29, 369 (1954).

    CAS  Google Scholar 

  7. Aufgenommen von Herrn Dr.P. Zoller, Basel, auf einem Perkin-Elmer-Spektrophotometer, Modell 21.

  8. A. Stoll, A. von Wartburg undJ. Renz, Helv. chim. Acta36, 1538 (1953).

    Google Scholar 

  9. A. Stoll, A. von Wartburg undJ. Renz führten Scilliglaucosidin durch Reduktion nachMeerwein-Ponndorf in Scilliglaucosidin-19-ol über. Herrn Prof. Dr.A. Stoll, Basel, sei auch hier für die freundliche Überlassung von Scilliglaucosidin herzlich gedankt.

  10. Reduktion vonΔ 4-Cholestenon mit LiAlH4 führt ebenfalls zu den zwei an C-3 epimerenΔ 4-Cholestenolen:H. Mc. Kennis undG. W. Gaffney, J. biol. Chem.175, 217 (1948).

    Article  Google Scholar 

  11. Pl. A. Plattner, H. Heusser undA. B. Kulkani, Helv. chim. Acta32, 265 (1949).

    Article  CAS  Google Scholar 

  12. A. Stoll, A. von Wartburg undJ. Renz, Helv. chim. Acta36, 1557, 1565 (1953).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Organisch-chemische Anstalt der Universität Basel, Switzerland

    A. Katz

Authors
  1. A. Katz
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

8. Mitteilung über die Glykoside vonBowiea vocubilis Harvey und 162. Mitteilung über Glykoside und Aglykone.

7. Mitt.:A. Katz, Helv. chim. Acta38, 1565 (1955).

161. Mitt.:H. Kündig-Hegedüs undO. Schindler, Helv. chim. Acta39, 904 (1956).

Rights and permissions

Reprints and permissions

About this article

Cite this article

Katz, A. Nachweis von Scilliglaucosidin in den Zwiebeln vonBowiea volubilisHarvey. Experientia 12, 285–286 (1956). https://doi.org/10.1007/BF02159610

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02159610

Search

Navigation