Experientia

, Volume 13, Issue 5, pp 183–183 | Cite as

The absolute configuration of valeroidine

  • G. Fodor
  • I. Vincze
  • J. Tóth
Kurze Mitteilungen

Keywords

Absolute Configuration 

Zusammenfassung

Auf Grund der Laktonregel vonHudson konnte dem (—) 3α·6β-Dihydroxy-tropan und (—) Valeroidin eine absolute Konfiguration zugeschrieben werden.

References

  1. 1.
    Summarized byG. Fodor, Exper.11, 129 (1955).Google Scholar
  2. 2.
    E. Hardegger andE. Ott, Helv. chim. Acta38, 312 (1955).Google Scholar
  3. 3.
    I. Vincze, J. Tóth, andG. Fodor, J. chem. Soc.1957, 1349.Google Scholar
  4. 4.
    C. S. Hudson, J. Amer. chem. Soc.32, 338 (1910).Google Scholar
  5. 4a.
    P. A. Levene andH. S. Simmes, J. biol. Chem.68, 737 (1926).Google Scholar
  6. 4b.
    The same rule has been adopted recently to γ- and δ-hydroxyamino acids, e.g. δ-hydroxyl-l-lysine byB. Witkop. The manuscript of this paper, prior to being published in Exper.12, 372 (1956), has been kindly submitted to one of us (G. F.).Google Scholar
  7. 5.
    G. Fodor, J. Tóth, I. Koczor, andI. Vincze, Chem. and Ind.1955, 1260.Google Scholar
  8. 6.
    For direct resolution of 3α·6β-tropandiol seeG. Fodor andL. Mészáros, Research, London5, 534 (1952).Google Scholar
  9. 6a.
    G. Fodor andÖ. Kovács, J. chem. Soc.1953, 2341.Google Scholar
  10. 7.
    For stereochemical notations of tropanes seeG. Fodor, J. Tóth, andI. Vincze, J. chem. Soc.1955, 304.Google Scholar
  11. 8.
    P. A. Levene andH. S. Simmes, J. biol. Chem.68, 737 (1926).Google Scholar
  12. 8a.
    The same rule has been adopted recently to γ- and δ-hydroxyamino acids, e.g. δ-hydroxy-l-lysine byB. Witkop. The manuscript of this paper, prior to being published in Exper.12, 372 (1956), has been kindly submitted to one of us (G. F.).Google Scholar
  13. 9.
    W. Klyne, Chem. and Ind.1954, 1198.Google Scholar
  14. 10.
    R. S. Cahn, C. K. Ingold, andV. Prelog, Exper.12, 81 (1956).Google Scholar

Copyright information

© Birkhäuser Verlag 1957

Authors and Affiliations

  • G. Fodor
    • 1
  • I. Vincze
    • 1
  • J. Tóth
    • 1
  1. 1.Institute of Organic Chemistry, the UniversitySzegedHungary

Personalised recommendations