Journal of thermal analysis

, Volume 30, Issue 2, pp 441–445 | Cite as

Thermodynamic properties of binary mixtures of α-Picoline and ISO-aliphatic alcohols

  • T. Kasprzycka-Guttman
  • K. Chreptowicz
Article

Abstract

The relationships enthalpy of mixing and excess Gibbs energyvs. composition were studied. We report hereH E andG E for 2-CH3-c-C5H4N (α-picoline)+ (1−x) CH3CH(OH)CH3, (1−x) CH3CHCH3CH2OH, (1 −x) CH3CH2(OH)CHCH3 or (1 −x) CH3C(CH3) (OH)CH3

Keywords

Polymer Alcohol Physical Chemistry Enthalpy Inorganic Chemistry 

Zusammenfassung

Die Beziehungen Zwischen Mischungsenthalpie und Gibbs'scher Überschuß- energie und der Zusammensetzung werden untersucht.H E undG E werden für die Systeme 2-CH3-C-C5H4N (α-Picolin) + (1−x) CH3CH(OH)CH3, (1 −x) CH3CHCH3CH2OH, (1−x) CH3CH2(OH)CHCH3 oder (1−x) CH3C(CH3)(OH)CH3

Резюме

Изучена взаимосвязь между энтальпией смешения, избыточной энергией Гиббса и составом смеси. Приве дены значенияН E и GE дл я смесей а-пиколин + (1-х) СН3СНОНСН3, (1-x) (СН3)2СН СН2ОН, (1-х) СН3СН2СНОНСН3, (1-х) СН3С(СН3)(ОН)СН3.

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References

  1. 1.
    T. Kasprzycka-Guttman and K. Iżycka, Pol. J. Chem. 54 (1980) 1775.Google Scholar
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    A. Országh and T. Kasprzycka-Guttman, Proc. First Intern. Conf. Calorimetry and Thermodynamics, Warsaw, 1969, p. 861.Google Scholar
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    M. Kiefer and F. Becker, Proc. Third Intern. Conference on Chemical Thermodynamics, Vienna, 1973, p. 126.Google Scholar
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Copyright information

© Wiley Heyden Ltd., Chichester and Akadémiai Kiadó, Budapest 1985

Authors and Affiliations

  • T. Kasprzycka-Guttman
    • 1
  • K. Chreptowicz
    • 1
  1. 1.Department of Chemical TechnologyWarsaw UniversityWarsawPoland

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