Zusammenfassung
Isoreserpiline-ψ-indoxyl wurde ausRauwolfia vomitoria Afzel isoliert. Durch eine einfache Synthese, ausgehend von Reserpilin, wurde die Struktur dieses neuen Alkaloids bewiesen.
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References
N. Finch andW. I. Taylor, J. Amer. chem. Soc.84, 1318, 3871 (1962).
N. Finch, C. W. Gemenden, I. H. Hsu, andW. I. Taylor, J. Amer. chem. Soc., in press.
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Such rearrangements are well known in model compounds and in two classes of non-tetrahydro-β-carboline alkaloids (inter alia,B. Witkop, Bull. Soc. Chim. France1954, 423.
M. F. Bartlett, D. F. Dickel, andW. I. Taylor, J. Amer. chem. Soc.80, 126 (1958).
The same alkaloid has also been recognized inRauwolfia ligustrina Roem. et Shult. byJ. M. Mueller (private communication) and inAspidosperma discolor A. DC. byN. Dastoor andH. Schmid, Exper.19, 297 (1963).
M. Shamma andJ. B. Moss J. Amer. chem. Soc.84, 1739 (1962).
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Finch, N., Taylor, W.I. & Ulshafer, P.R. Rauwolfia alkaloids XLVII isoreserpiline-ψ-indoxyl, its isolation, synthesis and structure. Experientia 19, 296 (1963). https://doi.org/10.1007/BF02150414
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DOI: https://doi.org/10.1007/BF02150414