Abstract
A new spectrum component is observed in Mössbauer spectra of thin body centered cubic Co layers prepared in Fe/Co superlattices doped with57Co. It is characterized by a large magnetic hyperfine field (31.2 T) and an isomer shift nearly equal to that of α-Fe. The decrease of the isomer shift in bcc Co with respect to hcp Co is consistent with smaller s to d charge transfer in bcc Co as compared to hcp Co. The cubic structure of the CoFe superlattices is evidenced with X-ray diffraction and ion-channeling measurements. The Fe/Co interface is investigated with conversion electron Mössbauer spectroscopy. It is shown that the interface alloy thickness is about six monolayers for growth temperatures up to 450 K and that increasing alloying occurs for higher growth temperatures.
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Dekoster, J., Bemelmans, H., Degroote, S. et al. Mössbauer spectroscopy investigation of body centered cubic Co in Co/Fe superlattices prepared with MBE. Hyperfine Interact 95, 191–198 (1995). https://doi.org/10.1007/BF02146314
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DOI: https://doi.org/10.1007/BF02146314