Skip to main content
Log in

Molecular rotations of polyhydroxycyclohexanes in relation to their structures

(−)-1,2/3,4-Cyclohexanetetrol

  • Kurze Mitteilungen
  • Published:
Experientia Aims and scope Submit manuscript

Zusammenfassung

Mit Hilfe der PM-Methode ist die molekulare Rotation von (−)-1,2/3,4-Cyclohexantetrol untersucht worden. Daraus geht hervor, dass diese Verbindung in wässeriger Lösung als Gemisch der C 1- und 1 C-Konstellationen vorliegt.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Literatur

  1. S. Yamana, J. Am. chem. Soc.86, 1606 (1964).

    Article  CAS  Google Scholar 

  2. N. A. B. Wilson andJ. Read, J. chem. Soc.1935, 1269.

  3. Th. Posternak andH. Friedli, Helv. chim. Acta36, 251 (1953).

    Article  CAS  Google Scholar 

  4. B. Magasanik, R. E. Franzl, andE. Chargaff, J. Am. chem. Soc.74, 2618 (1952).

    Article  CAS  Google Scholar 

  5. S. Yamana, Bull. chem. Soc. Japan33, 1741 (1960).

    Article  CAS  Google Scholar 

  6. L. P. Kuhn, J. Am. chem. Soc.74, 2492 (1952);76, 4323 (1954).

    Article  CAS  Google Scholar 

  7. As it has two OH groups intrans orientation, (−)-1/2-cyclohexanediol is believed to exist, in water solution, almost perfectly in C 1 conformation (having two equatorial OH groups). SeeJ. S. Brimacombe, A. B. Foster, M. Stacey, andD. H. Whiffen, Tetrahedron4, 351 (1958).

    Article  CAS  Google Scholar 

  8. R. A. Pickering andC. C. Price, J. Am. chem. Soc.80, 4931 (1958).

    Article  CAS  Google Scholar 

  9. M. D. Joesten andR. S. Drago, J. Am. chem. Soc.84, 3817 (1962).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Part III. Part II, seeS. Yamana, Bull. chem. Soc. Japan34, 1212 (1961).

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yamana, S. Molecular rotations of polyhydroxycyclohexanes in relation to their structures. Experientia 21, 305–307 (1965). https://doi.org/10.1007/BF02144680

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02144680

Keywords

Navigation