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Stereochemistry of corydaline and related alkaloids

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Zusammenfassung

Die stereochemische Zuordnung des Alkaloids Corydalin gelang auf Grund von konformationsanalytischen und spektroskopischen Daten. Grundsätzliche Überlegungen, unter Berücksichtigung gewisser chemischer Beziehungen, erlauben die stereochemische Zuordnung für Corybulbin, Isocorybulbin, Base II, Thalictracavin und Thalictrofolin.

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Literatur

  1. H. W. Bersch, Archiv. der Pharm.291, 595 (1958).

    Article  CAS  Google Scholar 

  2. Y. Kondo, J. pharm. Soc. Japan83, 1017 (1963).

    Article  CAS  Google Scholar 

  3. F. Bohlmann, Chem. Ber.91, 2157 (1958);92, 1798 (1959).

    Article  CAS  Google Scholar 

  4. E. Wenkert andD. K. Roychaudhury, J. Am. chem. Soc.78, 6417 (1956).

    Article  CAS  Google Scholar 

  5. The chemical shift of the C(13)-methyl was similar to that reported for 1(eq)-methylquinolizidine (T. M. Moynehan, K. Schofield, R. A. Y. Jones, andA. R. Katrisky, J. chem. Soc.1962, 2637).

  6. R. H. F. Manske, J. Am. chem. Soc.75, 4928 (1953).

    Article  CAS  Google Scholar 

  7. H. Taguchi andI. Imaseki, J. pharm. Soc. Japan84, 955 (1964).

    Article  CAS  Google Scholar 

  8. C. Tani, N. Takao, S. Takao, andK. Tagahara, J. pharm. Soc. Japan82, 751 (1962).

    Article  CAS  Google Scholar 

  9. R. H. F. Manske, Can. J. Res.21B, 111 (1943).

    Article  Google Scholar 

  10. H. Corrodi andE. Hardegger, Helv. chim. Acta39, 889 (1956).

    Article  CAS  Google Scholar 

  11. G. G. Lyle, J. org. Chem.25, 1779 (1960).

    Article  CAS  Google Scholar 

  12. See alsoA. Brossi, M. Baumann, F. Burkhardt, R. Richie, andJ. R. Frey, Helv. chim. Acta45, 2219 (1962).

    Article  CAS  Google Scholar 

  13. M. Ohta, H. Tani, andS. Morozumi, Chem. pharm. Bull.12, 1072 (1964).

    Article  CAS  Google Scholar 

  14. J. H. Brewster, Tetrahedron13, 106 (1961).

    Article  CAS  Google Scholar 

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Protoberberine alkaloids, Part 1.

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Jeffs, P.W. Stereochemistry of corydaline and related alkaloids. Experientia 21, 690–692 (1965). https://doi.org/10.1007/BF02138473

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