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17β-Hydroxymethyl-Steroide: Darstellung von Derivaten des 17β-Hydroxymethyl-4-androsten-3-ons

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Summary

Starting from methyl 3-oxo-4-etienate, the authors prepared 17β-hydroxymethyl-4-androsten-3-one and 11β-hydroxy-17β-hydroxymethyl-4-androsten-3-one. Chlorination of 17β-acetoxymethyl-4-androsten-3-one yielded 4-chloro-17β-acetoxymethyl-4-androsten-3-one. 17β-Hydroxymethyl-1, 4-androstadien-3-one was obtained from 17β-hydroxymethyl-4-androsten-3-one, both by chemical and biological methods.

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Authors and Affiliations

  1. Wissenschaftliche Laboratorien des VEB Jenapharm, Jena, DDR

    A. Schubert & S. Schwarz

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  1. A. Schubert
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  2. S. Schwarz
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Schubert, A., Schwarz, S. 17β-Hydroxymethyl-Steroide: Darstellung von Derivaten des 17β-Hydroxymethyl-4-androsten-3-ons. Experientia 21, 688–690 (1965). https://doi.org/10.1007/BF02138472

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