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Low-temperature oxidation of CO to CO2 in solutions of halide complexes of Pt and heteropolyacid (HPA)

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Abstract

Kinetics of oxidation of Co to CO2 in solutions of halide complexes of Pt(IV) and HPA at room temperature has been studied. A reaction mechanism is suggested. The catalyst Pt+HPA is stable at T=0–50°C and 0.9<pH<2.5.

Abstract

Изучена кинетика окисления CO в CO2 в растворах галоидных комплексов Pt(IV) и ГПК ири комнатных температурах. Предложен механизм реакции. Катализатор Pt+ГПК стабильно работает при 0–50°C и 0,9<pH<2,5.

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Authors and Affiliations

  1. Institute of Catalysis, 630090, Novosibirsk, Russia

    E. G. Zhizhina & K. I. Matveev

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  1. E. G. Zhizhina
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  2. K. I. Matveev
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Zhizhina, E.G., Matveev, K.I. Low-temperature oxidation of CO to CO2 in solutions of halide complexes of Pt and heteropolyacid (HPA). React Kinet Catal Lett 47, 255–262 (1992). https://doi.org/10.1007/BF02137658

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  • DOI: https://doi.org/10.1007/BF02137658

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