Abstract
The cracking of hydrocarbons over zeolites is accompanied by a significant production of coke, which causes their rapid deactivation. The coking and deactivation rates depend very much on the reactant. This makes necessary to compare the reactivities for the same coke content but not for the same time on stream.
Abstract
Обжиг углеводородов на цеолитах сопровождается значительным образованием кокса, который вызывает быструю дезактивацию цеолитов. Скорости обжига и дезактивации сильно зависят от реагента. Поэтому следует сравнивать реактивности при одинаковых содержаниях кокса, а ие при одинаковых временах на потоке.
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References
I. Mochida, Y. Yoneda: J. Catal.,7,386(1967);7,393(1967);8,223(1967)
M. Kraus, V. Bazant: Proc. Fifth Intern. Congress on Catalysis (J.W. Hightower Ed.), North-Holl and Publishing Company, Amsterdam, Vol. 2, 1073 (1973).
R. Maurel, M. Guisnet, G. Perot: J. Chim. Phys.,68, 573 (1971).
B. Coq, R. Durand, F. Fajula, C. Moreau, A. Finiels, B. Chiche, F. Figueras, P. Geneste: Heterogeneous Catalysis and Fine Chemicals (M. Guisnet et al., Eds), Studies in Surface Science and Catalysis, Vol. 41, p. 241. Elsevier, Amsterdam, 1988.
H. Pines: J. Catal.,78, 1 (1982).
L. Fors: Catalysis Reviews8, 65 (1973).
M. Guisnet: Catalysis by Acids and Bases (B. Imelik et al., Eds.), Studies in Surface Science and Catalysis, Vol. 20, p.283, Elsevier, Amsterdam, 1985.
D.M. Brouwer: Chemistry and Chemical Engineering of Catalytic Processes, (R. Prins and G.C.A. Schuit Eds.) NATO ASI series, Vol. 39, p.137, Sijthoff and Noordhoff, Alphen aan den Rijn, 1980.
J. Weitkamp, P.A. Jacobs, J.M. Martens: Appl. Catal.,8, 123 (1983).
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Lin, L., Gnep, N.S. & Guisnet, M. A procedure for comparing the reactivity of different hydrocarbons in cracking over zeolites. React Kinet Catal Lett 42, 133–138 (1990). https://doi.org/10.1007/BF02137629
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DOI: https://doi.org/10.1007/BF02137629