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Photochemical transformations of 6-Amino-penicillanic acid and phenoxymethylpenicillin

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Zusammenfassung

Bei der Bestrahlung von 6-Aminopenicillansäure mit UV-Licht entstehen Aminomethylpenicillin (Id), N-Formylpenicillamin (II) und ein Stoff der Summenformel C5H9NS, der vermutlich Struktur III besitzt. Phenoxymethylpenicillin wird bei der UV-Bestrahlung in ein Gemisch vonp- undo-Hydroxybenzylpenicillin umgewandelt.

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Godtfredsen, W.O., von Daehne, W. & Vangedal, S. Photochemical transformations of 6-Amino-penicillanic acid and phenoxymethylpenicillin. Experientia 23, 280–281 (1967). https://doi.org/10.1007/BF02135687

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