Abstract
The commercial product Supercypermetrin (3-phenoxy-α-cyanobenzyl-3-(2,2-dichlorovinyl)-2-(2,2-dimetyl)-cyclopropanecarboxylate) [SCM] in the liquid form was included in the zeolitic host. A natural zeolitic material of clinoptilolite type [CT] from a Slovakian deposit was used. The chemical control of the guest desorption was used for checking the existence of a new inclusion compound. The desorption of the insecticide under relatively drastic conditions (12 g of product in 200 ml H2O) showed a hindered and regulated release of the insecticide. Thermal curves obtained by means of a derivatograph and IR spectra were used for the study of the insecticide [SCM] enclosed (10%) in the zeolitic host and its desorption.
Similar content being viewed by others
References
P. Mézeš, Diploma Thesis, KACh PF UPJŠ. Košice 1994.
A. Sopková and P. Mézeš, Proc. of Termanal '94, 4.–7. 10. 1994 Vysoké Tatry 1994, p. 9.
J. Incl. Phenom., Vol. 1–18 (1983–1994).
A. Sopková, Molekulové zlučeniny — textbook. ES UPJŠ, Košice, 1986.
A. Sopková, J. Incl. Phenom., 14 (1992) 5.
E. Janoková-Hanzelová, Diploma Thesis, KACh PF UPJŠ, Košice, 1992.
A. Sopková and J. Bubanec, Chemicky průmysl, 38/63 (1988) 11.
A. Sopková, J. Bubanec, A.and Mihalič, Rudy, 36 (1988) 288.
P. Mondík and A. Sopková, J. Incl. Phenom., 13 (1992) 101.
P. Mondík, A. Sopková, G. Suchár and T. Wadsten, Proc 4th Intern. Seminar: Inclusion Coumpounds, Stará Lesná, 4.–9. June 1991, 1991 p. 49.
M. Reháková, A. Sopková, M. Casciola and Zd. Bastl, Solid State Ionics, 66 (1993) 189.
J. G. Scott, Pyrerthroid Insecticides, Atlas of Science, Pharmacology, 1989, p. 125.
F. Pechar and D. Rykl, Geologica Carpathica, Bratislava, (1982) 211.
J. E. D. Davies, in Inclusion Coumpound, Vol 3. (J. L. Atwood, J. E. D. Davies and D. D. MacNicol eds.). Academic Press, London 1984, p. 41.
A. K. Galwey, J. Thermal Anal., 41 (1994) 267.
A. Sopková, P. Mondík and M. Reháková, S. T. P. Pharma Sci., 4 (1994) 366.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Sopková, A., Mézeš, P. About the inclusion of an insecticide in zeolitic materials. Journal of Thermal Analysis 46, 471–478 (1996). https://doi.org/10.1007/BF02135024
Issue Date:
DOI: https://doi.org/10.1007/BF02135024