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Substoichiometric determination of manganese in a synergistic extraction system and its application to the analysis of biological materials

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Abstract

The substoichiometric isotope dilution analysis for manganese(II) in a synergistic extraction system of a chelating agent and a neutral ligand is described. The substoichiometric extarction is based on a substoichiometric amount of 2-thenoyltrifluoroacetone and an excess of 1,10-phenanthroline. The recommended condition and the reproducibility of the present system were examined. The present method was applied for NBS-SRM tomato leaves and NIES-SRM chlorella, and very good results with high accuracy and precision were demonstrated.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Tohoku University, Sendai, (Japan)

    N. Suzuki, S. Nakamura & H. Imura

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  1. N. Suzuki
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  2. S. Nakamura
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  3. H. Imura
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Suzuki, N., Nakamura, S. & Imura, H. Substoichiometric determination of manganese in a synergistic extraction system and its application to the analysis of biological materials. Journal of Radioanalytical and Nuclear Chemistry, Articles 81, 37–48 (1984). https://doi.org/10.1007/BF02132919

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  • DOI: https://doi.org/10.1007/BF02132919

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