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Reaction Kinetics and Catalysis Letters

, Volume 33, Issue 2, pp 387–392 | Cite as

Poly(vinylpyridine) complexes of palladium as hydrogenation catalysts. Effect of polymeric ligand structure

  • D. V. Sokolskii
  • A. K. Zharmagambetova
  • S. G. Mukhamedzhanova
  • E. A. Bekturov
  • S. E. Kudaibergenov
Article

Abstract

The title complexes exhibit high catalytic activity, selectivity and stability in hydrogenation of allyl alcohol. The structure of a polymeric ligand (i.e. the position of the nitrogen atom in the pyridine ring) affects catalyst activity. According to the hydrogenation rates of allyl alcohol, the complexes studied are arranged in the sequence: P4VP-Pd>P2VP-Pd>P2M5VP-Pd.

Keywords

Hydrogenation Nitrogen Alcohol Physical Chemistry Catalysis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Показана высокая каталитическая активность, избира-тельность и стадильность комплексов в реакции гидро-генизации аллилового спирта. Строение полимерного комплекса (положение азота в пиридиновом кольце) влияет на активность катализаторов. По уменьшению скорости гидрирования аллилового спирта изученные комплексы располагаются в ряд: П4ВП-Рд>П2ВП-Pd>П2М5ВП-Пд.

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Copyright information

© Akadémiai Kiadó 1987

Authors and Affiliations

  • D. V. Sokolskii
    • 1
  • A. K. Zharmagambetova
    • 1
  • S. G. Mukhamedzhanova
    • 1
  • E. A. Bekturov
    • 1
  • S. E. Kudaibergenov
    • 1
  1. 1.Institute of Organic Catalysis and ElectrochemistryAlma-AtaUSSR

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