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Reactivity of aromatic nitrons with alkyl and alkylperoxyl radicals

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Abstract

Reactivity of aromatic nitrons in reactions with alkyl and alkylperoxyl radicals has been investigated. Rate constants of these reactions obey the Hammett correlation equation that provides positive reaction constants ρ.

Abstract

Изучена реакционная способность ароматических нитронов в реакции с алкильными и алкилпероксильными радикалами. Константы скорости этих реакций подчиняются корреляционному уравнению Гаммета, из которого следует положительное значение константы реакционной серии ρ.

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Authors and Affiliations

  1. State University, 450074, Ufa, USSR

    A. Ya. Gerchikov & V. S. Martemiyanov

  2. Institute of Chemical Physics, 117977, Moscow, USSR

    I. Sh. Nasyrov, N. A. Akmanova & E. T. Denisov

Authors
  1. A. Ya. Gerchikov
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  2. I. Sh. Nasyrov
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  3. N. A. Akmanova
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  4. V. S. Martemiyanov
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  5. E. T. Denisov
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Gerchikov, A.Y., Nasyrov, I.S., Akmanova, N.A. et al. Reactivity of aromatic nitrons with alkyl and alkylperoxyl radicals. React Kinet Catal Lett 33, 317–322 (1987). https://doi.org/10.1007/BF02128082

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  • DOI: https://doi.org/10.1007/BF02128082

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