Skip to main content
SpringerLink
Log in

Catalytic properties of phosphorus-containing rhenium complexes in the hydrogenation of hexene-1

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Rhenium (V, VI) complexes with organophosphorus ligands proved to be catalytically active in hexene-1 hydrogenation. The kinetics of this process catalyzed by ReOCl3(PPh3)2 has been examined. The organic ligand in the coordination sphere of rhenium complexes was found to affect selectivity to olefin bonds or nitro groups in the hydrogenation of hydrocarbons.

Abstract

Комплексы рения(V, VI) с фосфорорганическими лигандами обладают каталитической активностью в реакции гидрирования гексена-1. Изучена кинетика этого процесса, катализируемого ReOCl3 (PPh3)2. Показано, что природа органического лиганда в координационной сфере рениевых комплексов влияет на избирательность их действия в реакциях гидрирования олефиновои связи или нитрогруппы углеводородов.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. P. Khrushch, A. E. Shilov: Kinet. Katal.,10, 466 (1966)

    Google Scholar 

  2. V. M. Belousov, G. I. Korenyako, Yu. N. Kukushkin, K. V. Kotegov, N. V. Fadeeva: Dokl. Akad. Nauk Ukr. SSR,12, 1011 (1979)

    Google Scholar 

  3. R. Mason, P. O. Whimp: J. Chem. Soc. A,18, 2709 (1969)

    Article  Google Scholar 

  4. K. V. Kotegov, Yu. N. Kukushkin, N. K. Kobilov, L. V. Konovalova: Zh. Neorg. Khim.,22, 1008 (1977)

    Google Scholar 

  5. K. V. Kotegov, G. N. Sedova, N. N. Kobilov, Yu. N. Kukushkin: Koord. Khim.,6, 897 (1980)

    Google Scholar 

  6. F. J. McQuillin: Homogeneous Hydrogenation in Organic Chemistry. Khimiya, Moskva 1980

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Physical Chemistry, 252028, Kiev, USSR

    V. M. Belousov, T. A. Palchevskaya, O. M. Negomedzyanova & K. V. Kotegov

Authors
  1. V. M. Belousov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. A. Palchevskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. M. Negomedzyanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. K. V. Kotegov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Belousov, V.M., Palchevskaya, T.A., Negomedzyanova, O.M. et al. Catalytic properties of phosphorus-containing rhenium complexes in the hydrogenation of hexene-1. React Kinet Catal Lett 28, 41–46 (1985). https://doi.org/10.1007/BF02116756

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02116756

Keywords

Search

Navigation