Summary
In a case of fatal arsenic intoxication samples of blood, liver and bile were analysed using atomic absorption spectroscopy. Different flames were used. The liver sample was ashed in a low temperature asher. The method is simple and requires a minimum of sample handling.
Zusammenfassung
In einem Fall von tödlicher Arsen-Intoxikation wurden Proben von Blut, Leber und Galle mit Hilfe von einem Atom-Absorptions-Spektrophotometer analysiert. Die Leberprobe wurde unter niedrigen Temperaturbedingungen verascht. Die Methode ist einfach und erfordert ein Minimum an Vorbehandlung.
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References
Barrowcliff, D.: The stoneleigh abbey poisoning case. Med.-leg. J. (Camb.)39, 79–90 (1971)
Bäumler, J., Im Obersteg, J., Shafer, R.: Determination of the level of arsenic in human bodies (population of Basle). Dtsch. Z. ges. gerichtl. Med.64, 56–61 (1968)
Fernandez, F. J.: Atomic absorption determination of gaseous hydrides utilizing sodium borohydride reduction. Atomic Abs. Newsl.12, 93–97 (1973)
George, G. M., Frahm, L. J., McDonnell, F.: Dry ashing method for the determination of total arsenic in animal tissues: Collaborative study. J. Ass. Off. Analyt. Chem.56, 793–797 (1973)
Grusz-Harday, E.: Arsengehalt des menschlichen Organismus bei Vergifteten in klinischen und tö dlichen Fällen. Arch. Toxikol.22, 164–175 (1966)
Heydorn, K.: Environmental variation of arsenic levels in human blood determined by neutron activation analysis. Clin. chim. Acta28, 349–357 (1970)
Hill, U. T.: Determination of arsenic in steels, iron ores, and spelters by atomic absorption. ASTM Special Technical Publication443, 83–89 (1969)
Kopp, J. P.: 1-ephedrine in chloroform as a solvent for silver diethyldithiocarbamate in the determination of arsenic. Analyt. Chem.45, 1786–1787 (1973)
Pearson, E. F., Pounds, C. A.: A case involving the administration of known amounts of arsenic and its analysis in hair. J. forens. Sci. Soc.11, 229–234 (1971)
Sanui, H.: Activated oxygen ashing of biological specimens for the microdetermination of Na, K, Mg, and Ca by atomic absorption spectrophotometry. Analyt. Biochem.42, 21–28 (1971)
Schroeder, H. A., Balassa, J. J.: Abnormal trace metals in man: Arsenic. J. chron. Dis.19, 85–106 (1966)
Schwab, R.: Kalte Trockenveraschung in der analytischen Chemie. Z. Anal. Chem.243, 208–209 (1968)
Spielholtz, G. I., Toraballa, G. C., Steinberg, R. J.: Determination of arsenic in coal and insecticides by atomic absorption spectroscopy. Mikrochim. Acta 918–923 (1971)
Weltz, B.: Personal communication (1973)
Williams, A. I.: The use of atomic-absorption spectrophotometry for the determination of copper, chromium and arsenic in preserved wood. Analyst97, 104–110 (1972)
Wyttenbach, A., Barthe, P., Martin, E. P.: The content of arsenic in the hair in a case of acute lethal arsenic poisoning. J. forens. Sci. Soc.7, 194–197 (1967)
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The authors are thankful to Asbjørn Granseth for technical assistance in this work.
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Norheim, G., Paus, P.E. Arsenic determination in autopsy material using atomic absorption spectroscopy. Z Rechtsmed 75, 127–130 (1974). https://doi.org/10.1007/BF02114708
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DOI: https://doi.org/10.1007/BF02114708