Topics in Catalysis

, Volume 3, Issue 3–4, pp 461–468 | Cite as

Active sites in methanol oxidation on Cu(110) determined by STM and molecular beam measurements

  • Michael Bowker


STM has been combined with molecular beam rate measurements to gain an understanding of the oxidative dehydrogenation of methanol to produce formaldehyde, both at the macroscopic and microscopic level. From this a model of the reaction is developed where the methanol initial reacts at very few active oxygen sites located at the short sides of oxygen islands on the Cu(110) surface. Such sites are very much rarer on a surface which is saturated with 0.5 monolayers of oxygen and the reaction rate is initially very low, but shows autocatalytic behaviour, rising in time as vacancies are created in the oxygen layer.


active site catalysis selective oxidation methanol copper 


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Copyright information

© J.C. Baltzer AG, Science Publishers 1996

Authors and Affiliations

  • Michael Bowker
    • 1
    • 2
  1. 1.Catalysis Research Centre, Department of ChemistryUniversity of ReadingReadingUK
  2. 2.IRC in Surface ScienceUniversity of LiverpoolUK

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