Abstract
Alkene oxidations with various oxidants (tert-butyl hydroperoxide, iodosylbenzene and molecular oxygen in the presence of isobutyraldehyde (IBA)) catalyzed by transition metal monosubstituted heteropolyanions, PW11MO n−39 (PW11M; M=CoII, MnII, CuII, TiIV, RuIV, VV and NbV), have been studied. Orders of catalytic activity of PW11M are different for the oxidants studied. Radical chain mechanisms are proposed fort-BuOOH and O2/IBA. Preliminary coordination of the oxidant to PW11M is not a necessary step of its homolytic activation. Epoxidation with PhIO requires its coordination to the catalyst and most likely includes the formation of active metal-oxo species.
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Kholdeeva, O.A., Grigoriev, V.A., Maksimov, G.M. et al. Alkene oxidation catalyzed by transition metal substituted Keggin-type heteropolyanions. Top Catal 3, 313–325 (1996). https://doi.org/10.1007/BF02113857
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DOI: https://doi.org/10.1007/BF02113857