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Cis-dichloro-bis (dimethylsulfoxyde) platine (II), cis PtCl2(DMSO)2: Nouvelle methode de preparation et etude de sa degradation thermique

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Abstract

The formation ofcis-PtCl2(DMSO)2 was achieved by simple contact between PtCl2 and DMSO. The congruent melting (220°) and thermal decomposition of the product were studied by DTA and TG. The formation reaction shows that the trans effect of Cl− is greater than that of DMSO.

Zusammenfassung

Cis-PtCl2(DMSO)2 wurde durch einfache Kontaktierung von PtCl2 und DMSO erhalten, Das Schmelzen (220°) und die thermische Zersetzung des Produktes wurden mittels DTA und TG untersucht. Die Bildungsreaktionen der Verbindung zeigen, daß der trans-Effekt von Cl− größer als der von DMSO ist.

Резюме

Простым контактиров анием хлористой плат ины с диметилсульфоксидо м (ДМСО) получено соединение цис-PtCl2(DMCO)2. Методами ДТА и ТГ изучено его конгруэн тное плавление (220°) и термич еское разложение, реа кции получения этого соед инения показали, что транс-эффект хлорид-и она больше, чем диметилсульфоксида.

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Authors and Affiliations

  1. Faculté de Pharmacie, Laboratoire de Chimie Minérale, Rue J. B. Clément, F 92290, Chatenay-Malabry

    P. Khodadad

  2. Faculté de Pharmacie 2B/S, Laboratoire de Chimie Physique, Boulevard Tonnellé, F 37032, Tours, France

    R. Ceolin

Authors
  1. P. Khodadad
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  2. R. Ceolin
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Khodadad, P., Ceolin, R. Cis-dichloro-bis (dimethylsulfoxyde) platine (II), cis PtCl2(DMSO)2: Nouvelle methode de preparation et etude de sa degradation thermique. Journal of Thermal Analysis 30, 1141–1147 (1985). https://doi.org/10.1007/BF02108545

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  • DOI: https://doi.org/10.1007/BF02108545

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