Journal of Radioanalytical and Nuclear Chemistry

, Volume 173, Issue 1, pp 137–140 | Cite as

Homogeneous isotope exchange between nickel(II) and bis(resacetophenone phenylhydrazone) nickel(II) complex

  • T. Gangaiah
  • P. Ramadevi
  • T. Balaji
  • G. R. K. Naidu


Isotope exchange behavior of bis-resacetophenone phenylhydrazone) nickel(II) complex with nickel(II) in tri-n-butyl phosphate and methanol medium has been studied. The studies were carried out at different temperatures varying the concentration of both metal ion and the complex. The results show that the complex is labile in the kinetic sense. Increase in temperature increases the isotope exchange rate. The increase in concentration also results in an enhancement of the rate of reaction.


Phosphate Methanol Physical Chemistry Nickel Inorganic Chemistry 
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  1. 1.
    YU. P. KITAEV, B. I. BUZYKIN T. V. TROEPOLSKAYA, Russ. Chem. Revs. (1970) 441.Google Scholar
  2. 2.
    M. KATYAL, Y. DUTT, Talanta, 22 (1975) 151.CrossRefGoogle Scholar
  3. 3.
    M. W. MOON, Ger. Offen, 2, 058, 156 U. S. Appl. 93, 496, 27.Google Scholar
  4. 4.
    M. W. MOON, E. G. GEMRICH, G. KAUGARDS, J. Agr. Food. Chem., 20 (1972) 888.CrossRefGoogle Scholar
  5. 5.
    J. G. PECCA, J. DOBRECKY, S. M. ALBONICO, J. Pharm. Sci., 60 (1971) 650.PubMedGoogle Scholar
  6. 6.
    P. UMAPATHY, N. A. RAJU, Indian J. Chem., 2 (1964) 248.Google Scholar
  7. 7.
    S. SRIHARI, N. A. RAJU, J. Indian Inst. Sci. 64 (1983) 45.Google Scholar
  8. 8.
    P. UMAPATHY, N. A. RAJU, Curri. Sci., 29 (1960) 428.Google Scholar
  9. 9.
    Y. Y. LIM, Aust. J. Chem., 27 (1974) 213.Google Scholar

Copyright information

© Akadémiai Kiadó 1993

Authors and Affiliations

  • T. Gangaiah
    • 1
  • P. Ramadevi
    • 1
  • T. Balaji
    • 1
  • G. R. K. Naidu
    • 1
  1. 1.Department of Chemistry, College of EngineeringSri Venkateswara UniversityTirupatiIndia

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