Skip to main content
SpringerLink
Log in

Mixed-valence states in TCNQ salts of monoalkylbiferrocenes and their mixed crystals with dialkyl derivative

  • Part I Chemical Structure and Bonding
  • Published:
Hyperfine Interactions Aims and scope Submit manuscript

Abstract

TCNQ salts of 1′-monoalkylbiferrocenes showed a temperature-independent trapped-valence state as expected for the unsymmetrical structure of cations. On the other hand, mixed crystals of 1′-monobutyl- and 1′.1‴-dibutylbiferrocenium+(TCNQ) −3 showed a temperature dependence of the mixed-valence states, showing that the lattice affects the mixed-valence states.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T.-Y. Dong, T. Kambara and D.N. Hendrickson, J. Am. Chem. Soc. 108 (1986) 4423.

    Article  Google Scholar 

  2. M. Kai, M. Katada and H. Sano, Chem. Lett. (1988) 1523.

  3. S. Nakashima, S. Iijima, I. Motoyama, M. Katada and H. Sano, Hyp. Int. 40 (1988) 315.

    Article  ADS  Google Scholar 

  4. S. Nakashima, Y. Masuda and H. Sano, Chem. Lett. (1988) 1851.

  5. S. Nakashima and H. Sano, Bull. Chem. Soc. Jpn. 62 (1989) 3012.

    Article  Google Scholar 

  6. M. Kai, I. Motoyama, M. Katada, Y. Masuda and H. Sano, Chem. Lett. (1988) 1037.

Download references

Author information

Author notes

  1. Satoru Nakashima

    Present address: Department of Chemistry, Odense University, Campusvej, 55-DK-5230, Odense M, Denmark

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Fukasawa, Setagaya-ku, 158, Tokyo, Japan

    Satoru Nakashima, Tsuneo Koura, Motomi Katada & Hirotoshi Sano

  2. Department of Chemistry, Faculty of Engineering, Kanagawa University, Rokkakubashi, Kanagawa-ku, 221, Yokohama, Japan

    Izumi Motoyama

Authors
  1. Satoru Nakashima
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Tsuneo Koura
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Motomi Katada
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Hirotoshi Sano
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Izumi Motoyama
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nakashima, S., Koura, T., Katada, M. et al. Mixed-valence states in TCNQ salts of monoalkylbiferrocenes and their mixed crystals with dialkyl derivative. Hyperfine Interact 53, 361–366 (1990). https://doi.org/10.1007/BF02101067

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02101067

Keywords

Search

Navigation