Skip to main content
SpringerLink
Log in

Structure of surface species in Mo/Al2O3 catalysts prepared through Mo(V) oxalate

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

EXAFS and RED structural studies of surface species of Mo/Al2O3 catalysts prepared through the anchoring of [Mo2O4(C2O4)2(H2O)]2− anion to γ-Al2O3 have shown that these surface metal complexes preserve a binuclear structure of the Mo(V) oxalate framework fragment.

Abstract

Методом EXAFS и РфРЭП изучено строение поверхностных соединений в катализаторах Mo/Al2O3, полученных закреплением аниона [Mo2O4(C2O4)2(H2O)2]2− на поверхности γ-Al2O3. Показано, что в поверхностных металлокомплексах сохраняется биядерная структура остовного фрагмента оксалата молибдена (V).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A.N. Startsev, O.V. Klimov, S.A. Shkuropat: React. Kinet. Catal. Lett.,41, 121 (1990).

    Article  Google Scholar 

  2. O.V. Klimov, A.N. Startsev: React. Kinet. Catal. Lett.,41, 135 (1990).

    Article  Google Scholar 

  3. M.C. Chakravorti, D. Bandyopadhyoa: Synth. React. Inorg. Metal-Org. Chem.,14, 443 (1984).

    Google Scholar 

  4. D.I. Kochubei, Yu.A. Babanov, K.I. Zamaraev, R.V. Vedrinskii, V.L. Kreisman, G.N. Kulipanov, L.N. Masalov, A.N. Skirinskii, V.K. Fedorov, B. Yu. Helmer, A.T. Shuvaev: in ESCA Structural Studies of Amorphous Bodies, Nauka, Novosibirsk, 1988.

    Google Scholar 

  5. A.G. McKale: J. Am. Chem. Soc.,110, 3763 (1988).

    Article  Google Scholar 

  6. J.H. Konnert, J. Karle: Acta Crystallogr.,A29, 702 (1973).

    Article  Google Scholar 

  7. F.A. Cotton, S.M. Morehouse: Inorg. Chem.,4, 1377 (1965).

    Article  Google Scholar 

  8. M.A. Porai-Koshits, L.O. Atovmyan: Crystallochemistry and Stereochemistry of Coordinated Molybdenum Compounds. Nauka, Moscow 1974.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Catalysis, 630090, Novosibirsk, USSR

    A. N. Startsev, O. V. Klimov, S. A. Shkuropat, P. E. Kolosov, V. K. Fedorov, S. P. Degtyarev & D. I. Kochubei

Authors
  1. A. N. Startsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. V. Klimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. A. Shkuropat
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. E. Kolosov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. K. Fedorov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. S. P. Degtyarev
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. D. I. Kochubei
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Startsev, A.N., Klimov, O.V., Shkuropat, S.A. et al. Structure of surface species in Mo/Al2O3 catalysts prepared through Mo(V) oxalate. React Kinet Catal Lett 41, 339–344 (1990). https://doi.org/10.1007/BF02097891

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02097891

Keywords

Search

Navigation