Abstract
The rates for reactions between methyl radicals and 1-heptene have been studied and the kinetic parameters log (k1/dm3 mol−1s−1)=8.4±0.1–(33.3±1.0) kJ/RT In 10 and log (k3/dm3 mol−1s−1)=7.5±0.2)–29.7±1.5) kJ/RT In 10 have been determined for addition and allyl-hydrogen abstraction, respectively.
Abstract
Измерены скорости реакций между метильным радикалом и 1-гептеном и получены кинетические параметры log (k1/Дм3 моль−1 сек−1)=(8,4±0,1)-(33,3±1,0) kJ/RT In 10 и log (k3/Дм3 моль−1 сек−1)=(7,5±0,2)–(29,7±15) kJ/RT In 10 для реакций присоединения и отрыва атома аллильного водорода.
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Dóbé, S., Réti, F. & Bérces, T. Kinetics of addition and allyl-hydrogen abstraction in the reaction between methyl radicals and 1-heptene. React Kinet Catal Lett 24, 413–416 (1984). https://doi.org/10.1007/BF02093467
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DOI: https://doi.org/10.1007/BF02093467