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γ-Initiated cotelomerization of ethylene and 1-hexene with ethyldichlorosilane. Calculation of relative yield of products

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Abstract

According to the suggested equations to describe the distribution of cotelomerization products, relative constants for chain propagation and transfer characterizing elementary steps of the process, and the character of the depencence between the product formation rate and the reactant concentrations have been established.

Abstract

Предложены уравнения, описывающие распределение продуктов в реакции сотеломеризации. Рассчитаны относителвные константы роста и передачи цепи, характеризующие элементарные стадии процесса. Установлен характер зависимости скорости образования продыктов от концентраций реагентов.

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References

  1. Yu. M. Lugovoi, A. G. Shostenko, P. A. Zagorets, V. P. Krapchatov: React. Kinet. Catal. Lett.,24, 329 (1983).

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Authors and Affiliations

  1. Chemico-Technological Institute, Moscow, USSR

    Yu. M. Lugovoi, A. G. Shostenko, P. A. Zagorets & V. P. Krapchatov

Authors
  1. Yu. M. Lugovoi
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  2. A. G. Shostenko
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  3. P. A. Zagorets
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  4. V. P. Krapchatov
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Lugovoi, Y.M., Shostenko, A.G., Zagorets, P.A. et al. γ-Initiated cotelomerization of ethylene and 1-hexene with ethyldichlorosilane. Calculation of relative yield of products. React Kinet Catal Lett 24, 335–340 (1984). https://doi.org/10.1007/BF02093452

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  • DOI: https://doi.org/10.1007/BF02093452

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