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Epoxidation of propylene with tert-butyl hydroperoxide in the presence of heterogeneous polymeric catalysts

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Abstract

A series of heterogeneous polymeric molybdenum containing catalysts on the basis of weak acid cation exchanger Amberlite IRC-84 in an organic and water medium was prepared. The catalysts activity and selectivity in the epoxidation of propylene with tert-butyl hydroperoxide are compared. Data about the chemical structure of catalytically active molybdenum containing centres of the modified cation exchanger were obtained.

Abstract

Была приготовлена серия гетерогенных катализаторов, содержащих полимерный молибден, на основе слабокислого катнонообменника Амберлита IRC-84 в органической и водной средах. Сравнивались каталитическая активность и селективность в эпоксидации пропилена с помощью трет.Бутилгидроперекиси. Были получены данные относительно химической структуры каталитически активного молибдена, содержащего центры модифицированного катионообменника.

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Authors and Affiliations

  1. Higher Institute of Chemical Technology, 8010, Burgas, Bulgaria

    R. S. Boeva & S. V. Kotov

  2. Institute of Organic Chemistry, Bulgarian Academy of Sciences, 1113, Sofia

    N. Jordanov

Authors
  1. R. S. Boeva
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  2. S. V. Kotov
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  3. N. Jordanov
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Boeva, R.S., Kotov, S.V. & Jordanov, N. Epoxidation of propylene with tert-butyl hydroperoxide in the presence of heterogeneous polymeric catalysts. React Kinet Catal Lett 24, 239–242 (1984). https://doi.org/10.1007/BF02093434

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  • DOI: https://doi.org/10.1007/BF02093434

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