Abstract
The formation of acidic effluents from mining waste materials is discussed and the chemisry involved explained. The bacteriumThiobacillus ferrooxidans plays an important role in acid production due to its ability to rapidly oxidize reduced forms of iron and sulphur which can result in the generation of H2SO4. The sulphide mineral pyrite (FeS2), often present in waste materials, is generally recognized as the chief source of acid mine drainage.
A small-scale test procedure has been developed which rapidly evaluates a waste material's capability to produce an acidic effluent. If the material is assessed as a potential acid producer, then scale-up testing procedures are available which can be used to simulate the characteristics of the effluents produced from a commercial-size waste dump.
During periods of little rainfall, localized biological activity may occur in wet areas of a waste dump, resulting in possible accumulation of soluble pollutants. The length of these dry periods greatly affects effluent characteristics during subsequent rainfalls.
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Bruynesteyn, A., Hackl, R.P. Evaluation of acid production potential of mining waste materials. Minerals and the Environment 4, 5–8 (1982). https://doi.org/10.1007/BF02093337
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DOI: https://doi.org/10.1007/BF02093337