Skip to main content
SpringerLink
Log in

Mechanism of decomposition of hydroperoxides in the presence of dithiophosphates, XI. Concentration effects of zinc diisopropyldithiophosphate

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

It has been established that the amount of tetralin, cumene and t-butyl hydroperoxide decomposed during the initial stages of the reaction (ΔROOH), referred to the initial concentration of dithiophosphate(Do) increases with decreasing Do. This effect can be explained by the conversion of Do to SO2 in the presence of excess ROOH, which leads to the heterolytic decomposition of the hydroperoxide.

Abstract

Было найдено, что количество гидроперекиси тетралина, кумена и трет-бутила (ΔROOH), разлагающегося на начальной стадии реакции, по сравнению к исходной концентрации дитиофосфата (Do), увеличивается с уменьшением последней, т.е с увеличением отношения ΔROOH/Do. Этот эффект может быть объяснен преврашением Do, в присутствии избытка ROOH, в SO2, который приводит к гетеролитическому разложению гидроперекиси.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. A. Oberright, S. J. Leonardi, A. P. Kozacik: Meeting of the ACS Division of Petroleum Chemistry, p. 159. Atlantic City 1958.

  2. I. V. Shkhinyants, M. A. Dzyubin, V. V. Sher, P. I. Sanin: Neftekhim.,13, 570 (1973).

    Google Scholar 

  3. S. Ivanov, I. Kateva, D. Shopov: Neftekhim.,12, 605 (1972).

    Google Scholar 

  4. I. Kateva, S. Ivavon: Erdöl Kohle,26, 77 (1973).

    Google Scholar 

  5. S. Ivanov, I. Kateva: Neftekhim.,11, 209 (1971).

    Google Scholar 

  6. D. Shopov, S. Ivanov, V. Ivanova: Rev. Inst. Francaise du Pétrol,22, 1520 (1967).

    Google Scholar 

  7. S. Ivanov, I. Kateva: Unpublished data

  8. G. Scott: Pure Appl. Chem.30, 267 (1972).

    Google Scholar 

  9. Y. C. W. Chien, C. R. Ross: J. Polym. Sci., Part A-1,10, 1579 (1972).

    Google Scholar 

  10. J. A. Howard, Y. Ohkatsu, Y. H. B. Chenier, K. U. Ingold: Can. J. Chem.,5, 1543 (1973).

    Google Scholar 

  11. J. A. Howard, H. B. Chenier: Can. J. Chem.,54, 300 (1976).

    Google Scholar 

  12. E. T. Denisov: Konstanty skorosti gomoliticheskikh zhidkofaznykh reaktsii. Nauka, Moscow 1971.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Organic Chemistry, Bulgarian Academy of Sciences, kv. Geo Milev Gl. V., 1113, Sofia, Bulgaria

    S. Ivanov & Y. Kateva

Authors
  1. S. Ivanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Y. Kateva
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ivanov, S., Kateva, Y. Mechanism of decomposition of hydroperoxides in the presence of dithiophosphates, XI. Concentration effects of zinc diisopropyldithiophosphate. React Kinet Catal Lett 6, 243–251 (1977). https://doi.org/10.1007/BF02084205

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02084205

Keywords

Search

Navigation