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Kinetics and mechanism of the interaction of 1,3-dioxacyclanes with esters

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Abstract

The interaction of 1,3-dioxalane, 1,3-dioxan and 1,3-dioxepane with amyl acetate is a reversible first order reaction with respect to both reagents and the catalyst. A mechanism for the reaction is suggested.

Abstract

Установлено, что взаимодействие 1,3-диоксолана, 1,3-диоксана и 1,3-диоксепана с амилацетатом является обратимой реакцией, имеющей первый порядок по каждому из реаентов и катализатору. Предложен механизм изученной реакции.

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References

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Authors and Affiliations

  1. Ufa Oil Institute, Bashkir State University, Ufa, USSR

    D. L. Rakhmankulov, I. L. Rakhmankulov, V. S. Martemiyanov & E. A. Kantor

Authors
  1. D. L. Rakhmankulov
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  2. I. L. Rakhmankulov
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  3. V. S. Martemiyanov
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  4. E. A. Kantor
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Rakhmankulov, D.L., Rakhmankulov, I.L., Martemiyanov, V.S. et al. Kinetics and mechanism of the interaction of 1,3-dioxacyclanes with esters. React Kinet Catal Lett 6, 181–186 (1977). https://doi.org/10.1007/BF02084195

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  • DOI: https://doi.org/10.1007/BF02084195

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