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Substituent effect in hydrogenative ring-opening of cyclobutanes on Pt/SiO2

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Abstract

The main direction of hydrogenative ring-opening of propylcyclobutane on Pt/SiO2 catalyst in the temperature interval of 373–673 K is the formation of n-heptane through cleavage of the sterically hindered C1−C2 bond. The unusual selectivity can be attributed to adsorption of both the ring and the propyl group on the catalyst. With increasing temperature, the selectivity of ring-opening approaches the statistically expected ratio.

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Authors and Affiliations

  1. Department of Organic Chemistry, Attila József University, Dóm tér 8, H-6720, Szeged, Hungary

    M. Bartók, B. Török, A. Molnár & J. Apjok

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  1. M. Bartók
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  2. B. Török
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  3. A. Molnár
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  4. J. Apjok
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Bartók, M., Török, B., Molnár, A. et al. Substituent effect in hydrogenative ring-opening of cyclobutanes on Pt/SiO2 . React Kinet Catal Lett 49, 111–118 (1993). https://doi.org/10.1007/BF02084036

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  • DOI: https://doi.org/10.1007/BF02084036

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