Abstract
Hydrogen and carbon monoxide chemisorption on supported platinum catalysts have been studied volumetrically and the adsorption heats determined by microcalorimetric measurements. From the results of this study is concluded that the use of reversible (or second) isotherms as a measure of weak chemisorption would appear inadequate.
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P.H. Emmett, S. Brunauer: J. Am. Chem. Soc.,59, 310 (1937).
G.B. McVicker, R.T.K. Baker, R.L. Garten, E.L. Kugler: J. Catal.,65, 207 (1980).
K. Balakrishnan, J. Schwank: J. Catal.,127 287 (1991).
Jr. Palmer, M.A. Vannice: J. Chem. Tech. Bistechnol.,30, 205 (1980).
C. Prado-Burguete, A. Linares-Solano, F. Rodriguez-Reinoso, Salinas-Martinez de Lecea: J. Catal.,128, 397 (1991).
A. Crucq, G. Lienard, L. Degols, A. Frennet: Appl. Surf. Sci.,17, 79 (1983).
A. Guerrero-Ruiz: Appl. Catal.,55, 21 (1989).
F. Rodriguez-Reinoso, I. Rodriguez-Ramos, C. Moreno-Castilla, A. Guerrero-Ruiz, J.D. Lopez-Gonzalez: J. Catal.,99, 171 (1986).
P.C. Gravelle: Adv. Catal.,22, 191 (1972).
J.M. Thomas, W.J. Thomas: Introduction to the Principles of Heterogeneous Catalysis. Academic Press, London 1967.
B. Sen, M.A. Vannice: J. Catal.,130, 9 (1991).
J.T. Richardson, T.S. Cole: J. Catal.,102, 419 (1986).
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Guerrero-Ruiz, A. Some aspects of reversible chemisorption on supported platinum catalysts. React Kinet Catal Lett 49, 53–60 (1993). https://doi.org/10.1007/BF02084028
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DOI: https://doi.org/10.1007/BF02084028