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Reaction Kinetics and Catalysis Letters

, Volume 11, Issue 4, pp 343–347 | Cite as

Chain transfer mechanism and kinetics in radical telomerization of ethylene with bromalkanes

  • A. G. Shostenko
  • V. E. Myshkin
  • V. Kim
Article
  • 34 Downloads

Abstract

Rate constants for chain transfer via bromoalkanes of various structure are estimated for primary, secondary and tertiary alkyl radicals and isokinetic dependences are shown to exist for their activation parameters. Isokinetic temperatures are calculated.

Keywords

Ethylene Physical Chemistry Catalysis Alkyl Radical Activation Parameter 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Для первичных, вторичных и третичных алкильных радикалов определены константы скорости реакций передачи цепи через бромалканы различного строения. Показано наличие изокинетических ззвисимостей для активационных параметров найденных констант скорости. Рассчитаны изокинетические температуры.

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References

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Copyright information

© Akadémiai Kiadó 1979

Authors and Affiliations

  • A. G. Shostenko
    • 1
  • V. E. Myshkin
    • 1
  • V. Kim
    • 1
  1. 1.Mendeleev Institute of Chemical TechnologyMoscowUSSR

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