Abstract
During the reactions of 8 isomeric alicyclic diols on Cu/Al and Cu catalysts, epimerization of the isomers was observed. The epimerization proceeds via a hydroxy-oxo intermediate.
Abstract
Наблюдена эпимеризация 8 изомерных алициклических диолов на Cu/Al и Cu катализаторах. Эпимеризация происходит через гидрокси-оксосоединение.
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References
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Part XLII of the series “Study of the transformations of diols and cyclic ethers”.
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Molnár, Á., Bartók, M. Stereochemistry of heterogeneous catalytic reactions; epimerization of alicyclic diols on copper catalysts. React Kinet Catal Lett 4, 425–429 (1976). https://doi.org/10.1007/BF02078633
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DOI: https://doi.org/10.1007/BF02078633