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Lattice oxygen removal from nearly stoichiometric V2O5

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Abstract

The activation energy of the removal of lattice oxygen connected with slight thermal dissociation of V2O5 was measured by the TPD method. The small value (24.7 kcal/mol O2) of this energy is discussed as the result of bivariant equilibria V2O5−x−O2 within the range x<0.01.

Abstract

Энергия активации удаления кислорода решетки, связанного со слабой термической диссоциацией V2O5, была измерена с помощью метода термодесорбции. Небольшая величина этой энергии приписывается существованию двухвариантного равновесия V2O5−x−O2 с интервалом x<0,01.

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  1. Institute of Chemistry, Jagiellonian University, Krupnicza 41, 30-060, Kraków, Poland

    R. Dziembaj

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  1. R. Dziembaj
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Dziembaj, R. Lattice oxygen removal from nearly stoichiometric V2O5 . React Kinet Catal Lett 9, 389–393 (1979). https://doi.org/10.1007/BF02077674

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  • DOI: https://doi.org/10.1007/BF02077674

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