Abstract
Adsorption of CO on a Rh/NaY zeolite has been studied by the ESR method using carbon monoxide enriched in13C. A complex with one unpaired electron delocalized over a rhodium nucleus and a CO molecule is shown to form upon adsorption. The unpaired electron density on the CO molecule is found to be about 0.25.
Abstract
Адсорбция CO на цеолите Rh/NaY была исследована с помощью метода ЭПР, используя окись углерода, обогащенную C13. Неспаренный электрон комплекса делокализуется на ядре родия и, как было показано, одна молекула CO образуется при адсорбции. Плотность неспаренного электрона в молекуле CO равна приблизительно 0,25.
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Atanasova, V.D., Shvets, V.A. & Kazansky, V.B. ESR study of carbon monoxide adsorption on rhodium exchanged Y zeolites. React Kinet Catal Lett 9, 349–352 (1979). https://doi.org/10.1007/BF02077667
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DOI: https://doi.org/10.1007/BF02077667