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Kinetics of oxidation of glycine by aqueous chlorine

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Abstract

The kinetics of oxidation of glycine with aqueous chlorine has been investigated. The reaction is first order with respect to both molecular chlorine and glycine and inverse first order with respect to H+. The effect of various factors on the initial rate has also been studied. The kinetic parameters have been calculated and a possible mechanism is proposed.

Abstract

Была исследована кинетика окисления глицина водным хлором. Реакция протекает по закону первого порядка по отношению к концентрации молекулярного хлора и глицина, и скорость обратно пропорциональна концентрации H+. Был исследован эффект различных факторов на начальную скорость, а также рассчитаны кинетические параметры. Постулируются возможный механизм протекания реакции.

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References

  1. V. P. Kudesia, S. K. Sharma: Acta Ciencia Indica,1, 21 (1975).

    Google Scholar 

  2. V. P. Kudesia, S. K. Nukherjee: Acta Ciencia Indica,3, 23 (1977).

    Google Scholar 

  3. V. P. Kudesia, S. K. Nukherjee: Ind. J. Chem.,15 A, 513 (1977).

    Google Scholar 

  4. V. P. Kudesia, S. K. Mukherjee: Ind. J. Chem. (submitted)

  5. N. M. M. Gowda, D. S. Mahadevappa: Monatsh. Chem.,110, 157 (1979).

    Google Scholar 

  6. F. Feigl: Spot Tests in Organic Analysis, p. 195, Elsevier, 1966.

  7. F. Feigl: Spot Tests in inorganic analysis, Elsevier, (1958), p. 238.

  8. A. I. Vogel: A Text Book of Quantitative Analysis, p. 326, Orient Longmans, 1967.

  9. M. S. Sherrill, E. P. Izard: J. Amer. Chem. Soc.,13, 1667 (1931).

    Google Scholar 

  10. N. Venkatasubramanian: J. Sci. Ind. Res.,20B, 541 (1961).

    Google Scholar 

  11. V. P. Kudesia: D. Sc. Thesis, Meerut University, 1977.

  12. V. P. Kudesia: Rev. Roum. Chim.,20, 1065 (1975).

    Google Scholar 

  13. V. P. Kudesia: Bull. Soc. Chim. Belg.,81, 623 (1972).

    Google Scholar 

  14. V. P. Kudesia: Rev. Roum. Chim.,24, 313 (1979).

    Google Scholar 

  15. C. J. Collins, N. S. Bowmann: Isotope Effects in Chemical Reactions p. 267. Van Nostrand Reinhold, New York 1970.

    Google Scholar 

  16. K. B. Wiberg: Chem. Rev.,55, 713 (1955).

    Google Scholar 

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Authors and Affiliations

  1. Chemical Laboratories, D. W. College, Neerut-1, U.P., India

    V. P. Kudesia & N. K. Sharma

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  1. V. P. Kudesia
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  2. N. K. Sharma
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Kudesia, V.P., Sharma, N.K. Kinetics of oxidation of glycine by aqueous chlorine. React Kinet Catal Lett 16, 49–54 (1981). https://doi.org/10.1007/BF02077027

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  • DOI: https://doi.org/10.1007/BF02077027

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