Skip to main content
SpringerLink
Log in

Confidence range for the determination of kinetic constants obtained from steady-state measurements

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

The problem of the confidence range for the determination of kinetic constants obtained from steady-state measurements is studied. The range of constants every point of which reproduces the results with equal accuracy is selected. As an illustration, the steady-state kinetic model of butadiene cyclooligomerization in the presence of low-valent Ni complexes is discussed.

Abstract

Псследуется вопрос об области многозначимости при определении кинетических констант на основании измерений, проведённых в стацтонарных условиях. Выдедяется область по константам, каждая точка внутри которой одинаково хорошо описывает измерения. В качестве иллюстрации анализируется стационарная кинетическая модель реакции циклоолигомеризация бутадиена в присутствии низковалентных комплексов никеля.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. V. Klibanov, S. I. Spivak, V. I. Timoshenko, M. G. Slinko: Dokl. Akad. Nauk SSSR,208, 1387 (1973).

    Google Scholar 

  2. G. A. Kokovin, V. A. Titov, Ya. M. Buzhdan, R. V. Dekhtyar: Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim.,2, 25 (1975).

    Google Scholar 

  3. M. I. Temkin: in Mechanism and Kinetics of Complex Catalytic Reactions, p. 57. Nauka, Moskva 1970.

    Google Scholar 

  4. U. M. Dzhemilev, A. G. Kukovinets, G. A. Tolstikov, S. I. Spivak, Z. Sh. Akhmadishin, A. S. Shmelev, F. S. Diachkovskii: Izv. Akad. Nauk SSSR, Ser. Khim. (in press).

Download references

Author information

Authors and Affiliations

  1. Institute of Petrochemical Technologies, Ufa, USSR

    Z. Sh. Akhmadishin, S. I. Spivak & A. S. Shmelev

Authors
  1. Z. Sh. Akhmadishin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. I. Spivak
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. S. Shmelev
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Akhmadishin, Z.S., Spivak, S.I. & Shmelev, A.S. Confidence range for the determination of kinetic constants obtained from steady-state measurements. React Kinet Catal Lett 16, 7–10 (1981). https://doi.org/10.1007/BF02077019

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02077019

Keywords

Search

Navigation