Abstract
A new magnesium oxide supported polysilazane ruthenium complex has been prepared and found to be capable of catalyzing the oxygenation of indene in 62.9% conversion to indanones without by-products under mild conditions, i.e. 1 atm oxygen and 80°C. The supported ruthenium complex was effective without need for a cocatalyst. Also, it can be reused several times without apparent loss of activity.
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Wang, Tj., Sun, Fy., Huang, My. et al. Catalytic behavior of a magnesium oxide supported polysilazane-ruthenium complex for the oxidation of indene with molecular oxygen to indanones. React Kinet Catal Lett 57, 147–152 (1996). https://doi.org/10.1007/BF02076133
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DOI: https://doi.org/10.1007/BF02076133