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Reaction Kinetics and Catalysis Letters

, Volume 57, Issue 1, pp 111–117 | Cite as

Salt effect on the micellar catalysis of the aquation of tris (3,4,7,8-tetramethyl-1,10-phenanthroline) iron(II) in H2O/Triton X-100 solvent system

  • Oladega Soriyan
  • Jide Ige
  • John Lambi
Article

Abstract

The effect of Na2SO4 and PhCOONa on the aquation of [Fe(Me4phen)3]2+ has been investigated in pure Triton X-100 as solvent. The rate and mechanism of the aquation are explained in terms of changes in the mobility, activity and structure of H2O in the restricted environment of water pockets in the Triton X-100 solvent.

Keywords

Micellar catalysis Triton X-100 aquation 

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Copyright information

© Akadémiai Kiadó 1996

Authors and Affiliations

  • Oladega Soriyan
    • 1
  • Jide Ige
    • 2
  • John Lambi
    • 2
  1. 1.Department of ChemistryMount Allison UniversitySackvilleCanada
  2. 2.Department of ChemistryObafemi Awolowo UniversityIle-IfeNigeria

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