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Kinetic model of CO oxidation on heterophase surface analyzed regarding COads spillover, I. Homotopic method. Effect of temperature and CO pressure

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Abstract

The homotopic method has been used to analyze the kinetic models of CO oxidation on two surface patches conjugated by COads spillover. On each patch reaction proceeds via a three-stage mechanism but with different constants. The stability of steady-states solution has been studied. COads spillover from one patch to another changes substantially the bifurcation picture of steady states and produces islands.

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Authors and Affiliations

  1. Federal Scientific Center, Boreskov Institute of Catalysis, 630090, Novosibirsk, Russia

    V. I. Savchenko & E. A. Ivanov

  2. Sobolev Institute of Mathematics, 630090, Novosibirsk, Russia

    S. I. Fadeev

Authors
  1. V. I. Savchenko
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  2. E. A. Ivanov
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  3. S. I. Fadeev
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Savchenko, V.I., Ivanov, E.A. & Fadeev, S.I. Kinetic model of CO oxidation on heterophase surface analyzed regarding COads spillover, I. Homotopic method. Effect of temperature and CO pressure. React Kinet Catal Lett 57, 55–60 (1996). https://doi.org/10.1007/BF02076120

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  • DOI: https://doi.org/10.1007/BF02076120

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