Skip to main content
SpringerLink
Log in

Transformation of a Pt/TiO2 catalyst from non-SMSI to SMSI studied by repeated H2−O2 titration

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Transformations of Pt/TiO2 catalyst between non-SMSI and SMSI states have been investigated by repeatedH2−O2 titration. The decline of capacity of H2 and O2 chemisorption and their reaction on Pt particles is accountable by reduction of superficial labile oxygen species in the temperature range of 298–573 K and an increase of surface oxygen vacancies on TiO2 above 573 K, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. E. Benson, M. Boudart:J. Catal.,4, 704 (1965).

    Google Scholar 

  2. D. E. Mears, R. C. Hansford:J. Catal.,9, 125 (1967).

    Google Scholar 

  3. J. Prasad, K. R. Murthy, P. G. Menon:J. Catal. 52, 515 (1978).

    Google Scholar 

  4. P. G. Menon, G. F. Froment:Appl. Catal. 1, 31 (1981).

    Google Scholar 

  5. S. J. Tauster, S. C. Fung, R. L. Garten:J. Am. Chem. Soc.,100, 170 (1978).

    Google Scholar 

  6. S. J. Tauster, S. C. Fung:J. Catal. 55, 29 (1978).

    Google Scholar 

  7. R. T. K. Baker, E. B. Prestridge, R. L. Garten:J. Catal.,59, 293 (1979).

    Google Scholar 

  8. R. T. K. Baker:J. Catal.,63, 523 (1980).

    Google Scholar 

  9. J. H. Hu, Z. P. Hong, Y. Z. Song, H. L. Wang:Spillover of Adsorbed Species (G. M. Pajonk, S. J. Teichner, J. E. Germin, Eds), p. 53. Elsevier, Amsterdam 1983.

    Google Scholar 

  10. J. C., Conesa, J. Soria:J. Phys. Chem.,86, 1392 (1982).

    Google Scholar 

  11. X. S. Li, Y. X. Chen, W. Z. Li: 6th U. S. A.-Japan-China Trilateral Symposium on Catalysis, June 7–11, 1993, Beijing China, p. 129.

  12. Y. X. Chen, Z. B. Wei, Y. X. Chen, H. X. Lin, Z. P. Hong, H. Q. Liu, Y. L. Dong, C. Y. Yu, W. Z. Li:J. Mol. Catal.,21, 275 (1983).

    Google Scholar 

  13. R. T. K. Baker, E. B. Prestridge, R. L. Garten:J. Catal.,56, 390 (1979).

    Google Scholar 

  14. J. C. Conesa, P. Malet, G. Munuera, J. Sanz, J. Soria:J. Phys. Chem.,88, 2986 (1984).

    Google Scholar 

  15. J. M. Herrmann, P. Pichat:J. Catal.,78, 425 (1982).

    Google Scholar 

  16. J. Sanz, J. M. Rojo, P. Malet, G. Munuera, M. T. Blasco, J. C. Conesa, J. Soria:J. Phys. Chem. Soc.,89, 5427 (1985).

    Google Scholar 

  17. J. A. Horsley:J. Am. Chem. Soc.,101, 2870 (1979).

    Google Scholar 

  18. M. A. Vannice, L. C. Hasselbing, B. Sen:J. Phys. Chem.,89, 2972 (1985).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 116023, Dalian, China

    Xin Sheng Li, Yan Xin Chen & When Zhao Li

Authors
  1. Xin Sheng Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yan Xin Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. When Zhao Li
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sheng Li, X., Chen, Y.X. & Li, W.Z. Transformation of a Pt/TiO2 catalyst from non-SMSI to SMSI studied by repeated H2−O2 titration. React Kinet Catal Lett 55, 235–243 (1995). https://doi.org/10.1007/BF02075856

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02075856

Keywords

Search

Navigation