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Radical addition of methyldichlorosilane to ketones

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Abstract

Radiation-induced reaction of methyldichlorosilane with ketones is shown to form products of radical addition to the carbonylic group. Competition kinetics method was used to determine relative rate constants of methyldichlorosilyl radical addition to some ketones.

Abstract

Показано, что радиационно-инициируемая реакция метилдихлорсилана с кетонами приводит к образованию продуктов присоединения по карбонильной группе. Методом конкурентной кинетики найдены относительные константы скорости для реакций присоединения метилдихлорсилильного радикала к ряду кетонов.

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References

  1. C. Chatgilialoglu, J. U. Ingold, J. C. Scaino: J. Am. Chem. Soc.,104, 5119 (1982).

    Google Scholar 

  2. J. Tsurugi, R. Nakao, T. Fukumoto: J. Am. Chem. Soc.,91, 4587 (1969).

    Google Scholar 

  3. R. Nakao, T. Fukumoto, J. Tsurugi: J. Org. Chem.,37, 76 (1972).

    Google Scholar 

  4. Yu. M. Lugovoi, A. G. Shostenko, N. P. Tarasova, I. A. Zaboluev, K. E. Danilov, C. Filliatre, G. Bourgeois: React. Kinet. Catal. Lett.,39, 379 (1989).

    Google Scholar 

  5. T. Dohmaru, Y. Nagata: J. Chem. Soc. Faraday Trans. 175, 2617 (1979).

    Google Scholar 

  6. N. U. Bryantseva, Yu. M. Lugovoi, A. G. Shostenko: React. Kinet. Catal. Lett.,37, 19 (1988).

    Google Scholar 

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Authors and Affiliations

  1. D. I. Mendeleev Institute of Chemical Technology, 125047, Moscow, USSR

    K. E. Danilov, Yu. M. Lugovoi, N. P. Tarasova, A. A. Churkin, A. G. Shostenko, L. G. Uranov & C. Filliatre

  2. Institute of Pine, Bordeaux, France

    G. Bourgeois

Authors
  1. K. E. Danilov
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  2. Yu. M. Lugovoi
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  3. N. P. Tarasova
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  4. A. A. Churkin
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  5. A. G. Shostenko
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  6. L. G. Uranov
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  7. C. Filliatre
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  8. G. Bourgeois
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Danilov, K.E., Lugovoi, Y.M., Tarasova, N.P. et al. Radical addition of methyldichlorosilane to ketones. React Kinet Catal Lett 41, 205–210 (1990). https://doi.org/10.1007/BF02075505

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  • DOI: https://doi.org/10.1007/BF02075505

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