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Inhibition of the adsorption of cyclohexene over a Pd/sepiolite catalyst by acrylamide

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Abstract

Cyclohexene acts as a powerful hydrogen donor over supported Pd catalysts. On the basis of the theory of competitive hydrogenations, this paper aims at accounting for the fact that acrylamide cannot be reduced by hydrogen transfer using cyclohexene as donor, whereas methacrylamide can.

Abstract

Циклогексен ведет себя как сильный донор водорода на нанесенных катализаторах Pd. Исходя из теории конкурентного гидрирования, авторы объясняют тот факт, что в то время как метакриламид гидрируется за счет переноса водорода от циклогексена, акриламид не гидрируется.

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Authors and Affiliations

  1. Department of Organic Chemistry, University of Córdoba, 14004, Córdoba, Spain

    M. A. Aramendia, V. Borau, C. Jiménez, J. M. Marinas, M. E. Sempere & F. J. Urbano

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  1. M. A. Aramendia
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  2. V. Borau
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  3. C. Jiménez
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  4. J. M. Marinas
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  5. M. E. Sempere
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  6. F. J. Urbano
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Aramendia, M.A., Borau, V., Jiménez, C. et al. Inhibition of the adsorption of cyclohexene over a Pd/sepiolite catalyst by acrylamide. React Kinet Catal Lett 41, 141–146 (1990). https://doi.org/10.1007/BF02075495

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  • DOI: https://doi.org/10.1007/BF02075495

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