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Simultaneous determination of kinetic and diffusion parameters for the water-gas shift reaction

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Abstract

The water-gas shift reaction was studied at 563–638 K over an industrial ferrochrome catalyst. The reaction rate data could be described by first order kinetics coupled to a diffusional resistance model for isothermal pellets. The model parameters were determined by simultaneous nonlinear regression.

Abstract

Реакцию водяного газа исследовали на промышленном феррохромном катализаторе при 563–683 К. Данные скорости реакции подчиняутся кинетике первого порядка совместно с моделью диффузионного сопротивления для изотермических гранул. Параметры модели были определены с помошью нелинейных регрессий.

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Salmi, T. Simultaneous determination of kinetic and diffusion parameters for the water-gas shift reaction. React Kinet Catal Lett 41, 1–5 (1990). https://doi.org/10.1007/BF02075473

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  • DOI: https://doi.org/10.1007/BF02075473

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