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Reaction Kinetics and Catalysis Letters

, Volume 43, Issue 1, pp 117–125 | Cite as

Kinetic studies on the aminolysis of O-(2,4-dinitrophenyl)-cyclopentanone oxime in benzene

  • Ajay K. Jain
  • Vinod K. Gupta
  • Pritam Singh
  • Anurag Kumar
Article
  • 17 Downloads

Abstract

The reaction of O-(2,4-dinitrophenyl) cyclopentanone oxime with four primary alkylamines and a secondary arylamine, pyrrolidine, in benzene has been investigated. In pyrrolidinolysis, a third order dependence on [amine] has been observed, which has been explained on the basis of a cyclic transition state. The aminolysis with primary alkyl amines shows a normal dependence of second order on [amine].

Keywords

Physical Chemistry Benzene Catalysis Transition State Kinetic Study 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Исследовали реакцию оксима O-(2,4-динитрофенил) циклопентанона с четырьмя первичными алкиламинами и вторичным ариламином-пирролидином в бензоле. В реакции с пирролидином скорость подчинялась третьему порядку по концентрации амина, что обьясняли на основе механизма циклического промежуточного состояния. Аминолиз первичными аминами протекает по обычному закону второго порядка от концентрации амина.

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Copyright information

© Akadémiai Kiadó 1991

Authors and Affiliations

  • Ajay K. Jain
    • 1
  • Vinod K. Gupta
    • 1
  • Pritam Singh
    • 1
  • Anurag Kumar
    • 1
  1. 1.Department of ChemistryUniversity of RoorkeeRoorkeeIndia

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