Skip to main content
SpringerLink
Log in

Europium-151 Mössbauer spectroscopic and XANES investigation of europium-exchanged Y-zeolite

  • Catalysis And Corrosion
  • Published:
Hyperfine Interactions Aims and scope Submit manuscript

Abstract

Eu3+ in ca. 10 wt% europium-exchanged Y-zeolite is partially reduced by treatment in hydrogen at 600°C to Eu2+. The reduction of Eu3+ is more readily achieved in Y-zeolite than in europium(III) oxide. The discrepancy in the extent of reduction as revealed by151Eu Mössbauer spectroscopy and near edge X-ray absorption fine structure (XANES) is associated with any difference in the recoil free fractions of Eu2+ and Eu3+ which may exist at 298 K and the enhanced sensitivity of the XANES to changes in the europium oxidation state.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C.N. Satterfield, in:Heterogeneous Catalysis in Practice (McGraw-Hill, New York, 1980) p. 174.

    Google Scholar 

  2. A.P. Bolton, in:Zeolite Chemistry and Catalysis, ACS Monograph 171, ed. J.A. Rabo (Am. Chem. Soc., Washington, 1976).

    Google Scholar 

  3. N.D. Spencer and G.A. Somorjai, Rep. Prog. Phys. 46 (1983) 1.

    Google Scholar 

  4. A.P. Bolton, J. Catal. 22 (1971) 9.

    Google Scholar 

  5. R.L. Firor and K. Seff, J. Am. Chem. Soc. 99 (1977) 7059.

    Google Scholar 

  6. R.L. Firor and K. Seff, Inorg. Chem. 17 (1978) 2144.

    Google Scholar 

  7. R.L. Firor and K. Seff, J. Am. Chem. Soc. 100 (1978) 976.

    Google Scholar 

  8. R.L. Firor and K. Seff, J. Am. Chem. Soc. 100 (1978) 978.

    Google Scholar 

  9. E.A. Samuel and W.N. Delgass, J. Chem. Phys. 62 (1975) 1590.

    Google Scholar 

  10. S.L. Suib, R.P. Zerger, G.D. Stucky, R.M. Emberson, P.G. Debrunner and L.E. Iton, Inorg. Chem. 19 (1980) 1858.

    Google Scholar 

  11. L.M. Aparicio, M.A. Ulla, W.S. Millman and J.A. Dumesic, J. Catal. 110 (1988) 330.

    Google Scholar 

  12. L.E. Iton, C.M. Broadbeck, S.L. Suib and G.D. Stucky, J. Chem. Phys. 79 (1983) 1185.

    Google Scholar 

  13. F.J. Berry, C. Greaves, R.C. Lobo and R. Strange, J. Chem. Soc. Faraday Trans. 87 (1991) 1405.

    Google Scholar 

  14. F.J. Berry, J.F. Marco and A.T. Steel, unpublished.

  15. G. Wortmann, Hyp. Int. 47 (1989) 179.

    Google Scholar 

  16. P.N. Ross, N.N. Delgass and J.R. Delgass, in:Catalysis, Vol. 12, ed. J.W. Hightower (North-Holland, Amsterdam, 1973) p. 597.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Chemistry, University of Birmingham, Edgbaston, B15 2TT, Birmingham, UK

    Frank J. Berry & José F. Marco

  2. Unilever Research, Port Sunlight Laboratory, L69 3JW, Bebington, Merseyside, UK

    Andrew T. Steel

Authors
  1. Frank J. Berry
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. José F. Marco
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Andrew T. Steel
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Berry, F.J., Marco, J.F. & Steel, A.T. Europium-151 Mössbauer spectroscopic and XANES investigation of europium-exchanged Y-zeolite. Hyperfine Interact 83, 347–350 (1994). https://doi.org/10.1007/BF02074297

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02074297

Keywords

Search

Navigation