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Kinetics of hydrogen oxidation in aqueous palladium(II) chloride and bromide. Activity of indiviual Pd(Cli) (i=0–4) complexes

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Abstract

The kinetics of molecular hydrogen oxidation by palladium(II) has been studied under homogeneous conditions, excluding Pd-black formation. The rate constants for PdCli(H2O)4−i complexes for i=0, 1, 2, 3 and 4 are 0.12±0.003; 3.4±0.4; 5.2±0.3; 2.34±0.07 and 0 M−1s−1, respectively.

Abstract

В гомогенных условиях, исключающих образование Pd-черни, изучена кинетика окисления H2 палладием (II). Константы скорости для комплексов PdCli(H2O)4−i равны 0,12±0,003; 3,4±0,4; 5,2±0,3; 2,34±0,07 и 0 М−1 сек−1, соответственно.

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Authors and Affiliations

  1. Institute of Physical Organic and Carbon Chemistry, Donetsk, USSR

    E. S. Rudakov, A. P. Yaroshenko & V. V. Zamashchikov

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  1. E. S. Rudakov
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  2. A. P. Yaroshenko
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  3. V. V. Zamashchikov
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Rudakov, E.S., Yaroshenko, A.P. & Zamashchikov, V.V. Kinetics of hydrogen oxidation in aqueous palladium(II) chloride and bromide. Activity of indiviual Pd(Cli) (i=0–4) complexes. React Kinet Catal Lett 11, 183–186 (1979). https://doi.org/10.1007/BF02074210

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  • DOI: https://doi.org/10.1007/BF02074210

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