Skip to main content
SpringerLink
Log in

A method to describe multicomponent reaction kinetics

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

A method is suggested to describe the kinetics of multicomponent reactions based on the definition of bond types whose conversion in similar reactions is characterized by the same rate constants, irrespective of the kind of the component which contains this bond. The method permits to obtain a description sensitive to the composition of reaction mixtures and at the same time to reduce significantly the number of kinetic parameters, since the number of bonds is much less than the number of components.

Abstract

Предложен метод описания кинетики многокомпонентых реакций, основанный на выделении типов связей, превращение которых в однотиных реакциях характеризуется одинаковыми константами скоростей, независимо от вида компонента, в котором данная связь находится. Метод позволяет получить описание, чувствительное к составу реагирующей смеси и в тоже время резко уменьшить число кинетических параметров, т. к. количество типов связей значительно меньше числа компонентоя.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. M. Tatevskii: Classical Theory of Molecular Structure and Quantum Mechanics. Khimiya, Moskva 1973.

    Google Scholar 

  2. S. B. Jaffe: Ind. Eng. Chem. Proc. Des. Dev.,13, 54 (1974).

    Google Scholar 

  3. G. I. Spivakovskii, A. I. Tishchenko, I. I. Zaslavskii, N. S. Wulfson: J. Chromatogr.,144, 1 (1977).

    Google Scholar 

  4. V. M. Tatevskii: Chemical Structure of Hydrocarbons and Regularities in their Physico-Chemical Properties. Moskovskii Gosudarstvennyi Universitet, Moskva 1953.

    Google Scholar 

  5. V. V. Korobov, A. V. Frost: in Physico-Chemical Properties of Individual Hydrocarbons (Ed. M. D. Tilicheev). Gostoptekhizdat, Moskva, Ser. 1, (1945); Ser. 2 (1947); Ser. 3 (1951).

    Google Scholar 

  6. S. S. Yuffit: Izv. Akad. Nauk SSSR, Ser. Khim.,10, 1748 (1962).

    Google Scholar 

  7. V. P. Sokolov, P. M. Zaidman, V. I. Shport, Yu. A. Alabuzhev: Some Peculiarities of Hydrocarbon Conversion Over Alumo-Platinum Catalysts Under Reforming Conditions. Preprint, Institut Kataliza, Novosibirsk 1976.

    Google Scholar 

  8. J. Henningsen, H. Bundgaard-Nielson: Brit. Chem. Engng.,15, 1433 (1970).

    Google Scholar 

  9. V. M. Tatevskii: Zh. Fiz. Khim.,32, 1226 (1958).

    Google Scholar 

  10. V. M. Tatevskii, S. S. Yarovoi: Zh. Fiz. Khim.,35, 2409 (1961).

    Google Scholar 

  11. S. S. Yarovoi, V. M. Tatevskii: Zh. Fiz. Khim.,35, 2417 (1961).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Research Institute of Monomers for Synthetic Rubber, Yaroslavl, USSR

    Yu I. Kuznetsov & E. V. Kuznetsova

Authors
  1. Yu I. Kuznetsov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. V. Kuznetsova
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kuznetsov, Y.I., Kuznetsova, E.V. A method to describe multicomponent reaction kinetics. React Kinet Catal Lett 13, 91–96 (1980). https://doi.org/10.1007/BF02074177

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02074177

Keywords

Search

Navigation