Reaction Kinetics and Catalysis Letters

, Volume 13, Issue 2, pp 85–90 | Cite as

Quantum-chemical studies of the interaction between furan and pyridine molecules and surface fragments of vanadium oxide catalysts

  • L. O. Golender
  • M. V. Shimanskaya


CNDO/2 studies of the interaction between furan and pyridine molecules and coordinatively unsaturated surface centers of vanadium oxide catalysts indicate that these molecules are more tightly bound and undergo more substantial changes in their electronic structure upon coordination to centers, containing reduced vanadium ions.


Oxide Physical Chemistry Catalysis Pyridine Vanadium 
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Нсследование методом ППДП/2 взаимдействия молекул фурана и пиридина с координационно-ненасыщенными центрами поверхности ванадий-окисного катализатора показало, что эти молекулы более прочно удержнваются и претерпевают более существенные изменения электронной структуры при координации над центрами, содержашими восстановленные ионы ванадия.


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Copyright information

© Akadémiai Kiadó 1980

Authors and Affiliations

  • L. O. Golender
    • 1
  • M. V. Shimanskaya
    • 1
  1. 1.Institute of Organic SynthesisRigaUSSR

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